Country for PR: Japan
Contributor: Kyodo News JBN
Friday, February 14 2020 - 16:00
AsiaNet
Nippon Shokubai Succeeds in Improving Performance of Electrolyte for All Solid Polymer Batteries
OSAKA, Japan, Feb. 14, 2020 /Kyodo JBN-AsiaNet/ --

Nippon Shokubai Co., Ltd. (hereinafter "Nippon Shokubai"), based in Osaka, has 
succeeded in improving the performance of electrolyte for all solid polymer 
batteries. All solid-state batteries using polymer electrolyte have features 
such as long life and high safety. On the other hand, polymer electrolyte has 
poor lithium ion conductivity. So it is necessary to heat the battery to more 
than 50 degrees Celsius. The newly developed polymer electrolyte shows high 
lithium conductivity performance. The operating temperature of the battery can 
be lowered near to room temperature. Therefore, new applications of all solid 
polymer batteries can be expected.

Logo: 
https://kyodonewsprwire.jp/prwfile/release/M104641/202002126721/_prw_PI3im_2ON4xM8r.jpg


Fig.1 Configuration of all solid polymer batteries
https://kyodonewsprwire.jp/prwfile/release/M104641/202002126721/_prw_PI1lg_pnC13OgQ.jpg


Nippon Shokubai developed a type of solid electrolyte consisting of 
polyethylene oxide for a lithium polymer battery and started commercial 
production around 2013. Generally, ionic conductivity of polyethylene oxide 
polymer electrolyte is lower than that of non-aqueous electrolyte for lithium 
ion batteries, and the lithium ionic transport number is about 0.1 to 0.2. At 
room temperature, lithium ions move very slowly through electrolyte. Therefore, 
in order to obtain stable performance, it was necessary to heat the battery to 
more than 50 degrees Celsius for accelerating lithium ionic transport.

Several studies to improve the lithium ionic transport number of polymer 
electrolyte have been reported, but most of them are not able to improve the 
performance because of the low ionic conductivity. Nippon Shokubai has 
introduced the original ionic conduction mechanism that can achieve a high 
performance. The company's newly developed electrolyte film has almost the same 
ionic conductivity and the lithium ionic transport number more than five times 
higher than that of the conventional polyethylene oxide electrolyte film.

Table 1. Ionic conductivity and lithium ionic transport number 
https://kyodonewsprwire.jp/prwfile/release/M104641/202002126721/_prw_PI2lg_7h9OatbV.jpg


The original electrolyte film has oxidation-reduction stability for lithium 
metal and 4V-class cathode active materials. The laminated cell battery 
fabricated using this technology exhibited extremely higher discharge 
characteristics than that of polyethylene oxide-based polymer. The dramatic 
improvement in battery performance leads to many potential benefits, including 
a shorter charging time, higher energy density, and reduction of 
battery-heating devices.

Nippon Shokubai will continue to contribute to improving the performance of 
polymer electrolyte for developing a new application. These research results 
are exhibited at a Nippon Shokubai booth at the Battery Japan 2020 exhibition, 
which will be held at Aomi Hall, Tokyo Big Sight, on February 26 (Wed.) to 28 
(Fri.).
 
About Nippon Shokubai Co., Ltd.: 
Since 1941, Nippon Shokubai has grown up its business with unique catalyst 
technology. Nippon Shokubai has supplied, for example, ethylene oxide, acrylic 
acid, automobile catalysts, process catalysts and so on. Among all, its global 
market share of superabsorbent polymer is the largest in the world now. Nippon 
Shokubai is a global chemical company operating under its corporate mission 
"TechnoAmenity--Providing affluence and comfort to people and society with our 
unique technology."  

http://www.shokubai.co.jp/en/


Source: Nippon Shokubai Co., Ltd.